Bis{4-chloro-2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}zinc(II)
نویسندگان
چکیده
The Zn atom in the title compound, [Zn(C(17)H(14)ClN(2)O)(2)], is N,O-chelated by two deprotonated Schiff base monoanionic ligands in a tetra-hedral coordination geometry. The Zn atom lies on a special position of site symmetry 2.
منابع مشابه
Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate
The Ni atom in the title compound, [Ni(C(17)H(15)N(2)O)(2)]·2C(3)H(7)NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyl-imino-meth-yl]phenolate ligand in a square-planar coordination environment. The mol-ecule is linked to a solvent mol-ecule by an indole-dimethyl-formamide N-H⋯O hydrogen bond.
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In the title compound, [Zn(C(12)H(11)N(2)O)(2)], the Zn(II) atom, lying on an inversion center, is coordinated by two O atoms and two N atoms from two salicylal Schiff base ligands in a distorted square-planar geometry. A three-dimensional network is formed by inter-molecular C-H⋯N hydrogen bonds and C-H⋯π contacts.
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In the title complex, [Cu(C(12)H(7)BrClN(2)O)(2)], the Cu(II) center is tetra-coordinated by two phenolate O and two azomethine N atoms from two independent bidentate 4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment. The inter-planar dihedral angles between the benzene and pyridi...
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In the title complex, [Ni(C(9)H(9)BrNO)(2)], the Ni(II) ion lies on an inversion centre and is coordinated in a slightly distorted square-planar geometry by two N atoms and two O atoms from two symmetry-related bidentate 4-bromo-2-(ethyl-imino-meth-yl)phenolate ligands. The complex forms a one-dimensional chain in the crystal structure through short C-H⋯Br contacts (H⋯Br = 3.009 Å).
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In the crystal structure of the title compound, [Co(C(13)H(9)N(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion is four-coordinated by two N atoms and two O atoms from two deprotonated 2-(1H-benzimidazol-2-yl)phenol ligands in a distorted tetra-hedral geometry. The dimethyl-formamide solvent mol-ecules are found inside a two-dimensional network structure formed by inter-molecular N-H⋯O hydrogen bonds linki...
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